I wonder when any global warming sceptic is going to come up with convincing reasons why ocean acidification is not something to worry about. In fact, when are they going to give it any attention at all.Over the history of the planet, there have been many sudden peaks in CO2 related to volcanic eruptions, releases from hydrothermal vents, and other natural events. When the pH of the ocean dips as a result of absorbing this excess gas, bottom sediments rich in calcium carbonate begin to dissolve, countering the increase in acidity. This buffering process occurs over 20,000 years, roughly the time it takes for water to circulate along the bottom from the Atlantic to the Pacific and back up to the surface several times. Currently, however, we are pouring man-made CO2 into the atmosphere at 50 times the natural rate. “That overwhelms the natural buffering system for maintaining balance in ocean chemistry,” the Carnegie Institution’s Caldeira says. “To find any parallel in the earth’s history you would have to look to a sudden violent shock to the system far in the geologic past.”
One such event occurred 55 million years ago at the so-called Paleocene-Eocene Thermal Maximum (PETM), when 4.5 million tons of greenhouse gases were released into the atmosphere. Just what triggered this enormous emission is not known, but scientists suspect volcanic activity may have begun the process. That may in turn have caused the planet to heat up enough to melt deposits of methane frozen in sediments on the ocean floor (something, incidentally, that could happen again), discharging even more potent greenhouse gases into the atmosphere and further heating the planet in an escalating feedback loop.
Whatever the exact cause of the CO2 release at the PETM, the earth warmed faster than at almost any other time in its history. The average temperature soared 9 degrees Fahrenheit, entire ecosystems shifted to higher latitudes, and massive extinctions occurred on land and, most telling, at sea. The abrupt rise of CO2 acidified the oceans. James Zachos, a paleo-oceanographer from the University of California at Santa Cruz, analyzed sediment cores obtained from deep drilling in the ocean and discovered that bottom-dwelling creatures with shells disappeared from the fossil record for a period of more than 40,000 years corresponding to the PETM. And once the oceans turned more acidic, Zachos says, they did not recover quickly: It took another 60,000 years before sediments again began to show a thick white streak indicative of fossilized shells.
Drastic as the PETM was, the event is tame compared with acidification today. “Back then,” Zachos says, “4.5 million tons of CO2 were released over a period of 1,000 to 10,000 years. Industrial activities will release the same amount in a mere 300 years—so quickly that the ocean’s buffering system doesn’t even come into play.”
UPDATE: I've noticed that the figure of 4.5 million tons of CO2 being released during PETM must be an error. If you follow the link in the article (about PETM,) it indicates it should be 4.5 Gt. Disappointing to see an error like that turn up at Discover, but I'll email them now!